Product ID:ALL CLEAR GRANULAR, CPE133519
MSDS Date:01/22/1993
FSC:6850
NIIN:00N078564
MSDS Number: CFPHV

OLIN CORPORATION

120 LONG RIDGE ROAD
STAMFORD, CT 06904
US

Emergency Phone: 800-654-6911

Info Phone: 203-356-3449

Cage: 99530

OLIN CORPORATION

4500 NORWALK, CT 06856-4500 US

Telephone: 203-750-3000/800-511-MSDS

Cage: 99530

CALCIUM HYPOCHLORITE (CERCLA)

CAS: 7778-54-3

RTECS: NH3485000

Fraction By Weight: 65-75%

OSHA PEL 0.5 PPM (CL)

ACGIH TLV: 0.5PPM/1STEL(CL)9495

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

SODIUM CHLORIDE

CAS: 7647-14-5

RTECS: VZ4725000

Fraction By Weight: 10-20%

OSHA PEL N/K

ACGIH TLV: N/K

CALCIUM CHLORATE

CAS: 10137-74-3

RTECS: FN9800000

Fraction By Weight: 0-5%

OSHA PEL N/K

ACGIH TLV: N/K

CALCIUM CHLORIDE

CAS: 10043-52-4

RTECS: EV9800000

Fraction By Weight: 0-5%

OSHA PEL N/K

ACGIH TLV: N/K

CALCIUM HYDROXIDE

CAS: 1305-62-0

RTECS: EW2800000

Fraction By Weight: 0-4%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 5 MG/M3; 9495

CALCIUM CARBONATE

CAS: 471-34-1

RTECS: FF9335000

Fraction By Weight: 0-4%

OSHA PEL N/K

ACGIH TLV: N/K

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 5.5-10%

OSHA PEL N/K

ACGIH TLV: N/K

SWELLING & SCAB FORMATION. PRLNG SKIN EXPOS MAY

RTECS: 9999999ZZ

IRRIT &/BURNS

RTECS: 9999999ZZ

INTESTINES, CHARACTERIZED BY NAUSEA, VOMIT, DIARR,

RTECS: 9999999ZZ

(RPTD) INHAL EXPOS MAY CAUSE IMPAIRMENT OF

RTECS: 9999999ZZ

SKIN EXPOS WOULD BE SIMILAR TO THOSE FROM SINGLE

RTECS: 9999999ZZ

THERE ARE NO KNOWN OR REPORTED EFFECTS FROM

RTECS: 9999999ZZ

REMOVE VICTIM TO FRESH

RTECS: 9999999ZZ

OF IGNIT. STOP SOURCE OF SPILL AS SOON AS POSS &

RTECS: 9999999ZZ

BY USE OF A WATER FOG. ALL H*2O UTILIZED TO ASSIST

RTECS: 9999999ZZ

MAY BE CONTAMD & MUST BE CONTAINED BEFORE DISP.

RTECS: 9999999ZZ

EXIT H*3O FOR AVAIL CHLORINE & PH. ADVISE LOCAL AUTH

RTECS: 9999999ZZ

ALL CONTAMD MATL IN A CLEAN DRY CNTNR & REMOVE TO A

RTECS: 9999999ZZ

CONTAMD SPILL MATL MAY BECOME HAZ WASTE. SPILL

RTECS: 9999999ZZ

THIS MATL MAY BE NEUT FOR DISP; YOU ARE REQUESTED TO

RTECS: 9999999ZZ

ANY SUCH OPERATIONS. PERSONAL PROT FOR EMER SPILL &

RTECS: 9999999ZZ

EXTRA PROT BEYOND THAT LISTED IN SECTION 8. IN A

RTECS: 9999999ZZ

STANDARD FIRE PROTECTIVE CLOTHING.

RTECS: 9999999ZZ

40 CFR 268 AND MUST BE MANAGED ACCORDING TO

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50 (ORAL, RAT):850 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:WARNING STATEMENT & WARNING
PROPERTIES:HARMFUL IF INHALED/INGEST. HARMFUL IF EXPOSED TO
SKIN/EYES. HUMAN RESPONSE DATA:ODOR THRESHOLD:APPROX 1.17
MG/CUBIC-METER (0.3 PPM) BASED ON ODOR OF CHLORINE. IM MED
DANGEROUS TO LIFE/HLTH:PROD HAS POTNTL TO BE IMMED DANGEROUS TO
LIFE/HLTH. ACUTE:INHAL:INHAL OF (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:THIS MATL IS IRRIT TO NOSE, MOUTH,
THROAT & LUNGS. IT MAY ALSO CAUSE BURNS TO RESP TRACT W/PRODUCTION
OF LUNG EDEMA WHICH CAN RSLT IN SHORTNESS OF BRTH, WHEEZING,
CHOKING, CHEST PAIN, & IMPAI RMENT OF LUNG FUNCTION. INHAL OF HIGH
CONCS CAN RSLT IN PERM LUNG DMG. EYE:SEVERE IRRIT &/BURNS CAN OCCUR
(SUPDAT)
Medical Cond Aggravated by Exposure:ASTHMA, RESPIRATORY AND
CARDIOVASCULAR DISEASE.

First Aid:EYES:IMMED FLUSH W/LRG AMTS OF H*2O FOR AT LEAST 15 MIN,
OCCAS LIFTING UPPER & LOWER EYELIDS. CALL MD AT ONCE. SKIN:IMMED
FLUSH W/H*2O FOR AT LEAST 15 MIN. CALL MD. IF CLTHG COMES IN CNTCT
W/PROD, IT SHOULD BE REMOVED IMMED & LAUNDERED BEFORE REUSE.
INGEST:IMMED DRINK LRG QTIES OF H*2O. DO NOT INDUCE VOMIT. CALL MD
AT ONCE. DO NOT GIVE ANYTHING BY MOUTH IF PERSON IN UNCON/IF HAVING
(ING 14)

Extinguishing Media:NOT APPLICABLE. MEDIA SUITABLE FOR SURROUNDING FIRE
.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . USE WATER TO COOL CONTAINERS EXPOSED TO FIRE. SEE
SECTION 7.
Unusual Fire/Explosion Hazard:DO NOT USE DRY EXTINGUISHERS, CONTAINING
AMMONIUM COMPOUNDS.

Spill Release Procedures:FOR ALL TRANSPORTATION ACCIDENTS, CALL
CHEMTREC AT 800-424-9300. REPORTABLE QTY:10 LBS. (AS CALCIUM
HYPOCHLORITE) PER 40 CFR 302.4. SMALL MITIGATION PROC:HAZ CONCS IN
AIR MAY BE FOUND IN LOCAL SPILL A REA & IMMED DOWNWIND. REMOVE ALL
SOURCES (ING 15)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT TAKE INTERNALLY. AVOID CNTCT
W/EYES, SKIN/CLTHG. UPON CNTCT W/SKIN/EYES, WASH OFF W/H*2O. KEEP
TIGHTLY SEALED.
Other Precautions:STORE IN A COOL, DRY WELL-VENT AREA. DO NOT STORE
>52C,125F. SHELF LIFE: 2YRS @ >52C & LOW HUMIDITY. FOR MORE
SPECIFIC INFORMATION CONTACT NEHC .

Respiratory Protection:WEAR NIOSH APPROVED RESPIRATOR.
Ventilation:USE LOCAL EXHAUST VENTILATION TO MINIMIZE DUST AND CHLORINE
LEVELS.
Protective Gloves:NEOPRENE/PVC.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER .
WEAR NEOPRENE/PVC BOOTS & APRONS TO AVOID SKIN AND EYE CONTACT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
PH:10.5-11.5 (1% SOLUTION). SOL IN H*2O: APPROX 18% @ 25 DEG C. (PROD
ALSO CNTNS CALCIUM HYDROXIDE & CALCIUM CARBONATE WHICH WILL LEAVE A
RESIDUE.) EFTS OF OVEREXP:FOLLOWING EYE EXPOS. CNTCT MAY CAUSE
IMPAIRMENT OF VISION & CORNEAL DMG. SKIN:DERMAL EXPOS CAN CAUSE
IRRIT &/BURNS CHARACTERIZED BY REDNESS, (ING 8)

pH:SUPDAT
Solubility in Water:SUPDAT
Appearance and Odor:WHITE, FREE FLOWING POWDER; CHLORINE-LIKE ODOR.

Stability Indicator/Materials to Avoid:YES
ACIDS, ORGANICS, NITROGEN CONTAINING CMPDS, DRY POWDER FIRE
EXTINGUISHERS, CORR, FLAMM/COMBUST MATLS.
Stability Condition to Avoid:HIGH TEMPERATURES > 125 DEG. F, HIGH
HUMIDITY.
Hazardous Decomposition Products:CHLORINE GAS.

Waste Disposal Methods:IF THIS PROD BECOMES WASTE, IT MEETS CRITERIA OF
HAZ WASTE AS DEFINED UNDER 40 CFR 261 & COULD HAVE FOLLOWING EPA
HAZ WASTE NUMBER:D001. IF THIS PROD BECOMES A WASTE, IT WILL BE A
HAZ WASTE WHICH IS S UBJECT TO LAND DISP RESTRICTIONS UNDER (ING
25)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.